DETAILED ACTION
Notice of Pre-AIA or AIA Status
The present application, filed on or after March 16, 2013, is being examined under the first inventor to file provisions of the AIA .
The text of those sections of Title 35, U.S. Code not included in this action can be found in a prior Office action.
Continued Examination Under 37 CFR 1.114
A request for continued examination under 37 CFR 1.114, including the fee set forth in 37 CFR 1.17(e), was filed in this application after final rejection. Since this application is eligible for continued examination under 37 CFR 1.114, and the fee set forth in 37 CFR 1.17(e) has been timely paid, the finality of the previous Office action has been withdrawn pursuant to 37 CFR 1.114. Applicant's submission filed on 4/13/2026 has been entered.
Response to Amendment
In response to the amendment received on 4/13/2026:
Claims 1-4 and 6-13 are pending in the current application. Claims 1 and 13 have been amended and Claims 5 and 14-16 have been canceled.
The cores of the previous prior art-based rejections have been maintained in light of the amendment and reworded to reflect the amended claims. All changes made to the rejection are necessitated by the amendment.
Claim Interpretation
All “wherein” clauses are given patentable weight unless otherwise noted. Please see MPEP 2111.04 regarding optional claim language.
Response to Arguments
Applicant's arguments have been fully considered.
Arguments directed at amended Claim 1
Applicant argues that the combination of Zeng and Hyun fails to render obvious the conductive materials now claimed.
The examiner respectfully disagrees. Hyun does disclose conductive materials of graphite, metal fiber, aluminum powder, nickel powder, zinc oxide, potassium titanate, titanium oxide, and polyphenylene derivatives as conductive materials appropriate for use in a battery (see pg. 8). As such, the combination of Zeng and Hyun would render the use of these materials in the claimed invention obvious, as is addressed in the new rejection of claim 1 below.
Claim Rejections - 35 USC § 103
Claims 1-4 and 7-13 are rejected under 35 U.S.C. 103 as being unpatentable over Zeng et al. CN-112072068-A (hereinafter referred to as Zeng) in view of Hyun et al. KR-20080015162-A (hereinafter referred to as Hyun).
Regarding Claim 1, Zeng discloses a positive electrode for a lithium secondary battery (see paragraphs [0002], [0004]-[0005], and [0007]) comprising:
a current collector 1 in Fig. 1 (see paragraphs [0007] and [0009]-[0011]);
a first coating layer (safety/security layer) 2 disposed on one or both surfaces of the current collector 1 and containing a first positive electrode active material in Fig. 1 (see paragraphs [0051]);
a layer (conductive layer) 3 disposed on the first coating layer 2 and having a binder and a conductive material dispersed in the binder (see paragraphs [0009]-[0010], [0051]); and
a second coating layer (active material layer) 4 disposed on the first coating layer 2 on which the conductive layer 3 is disposed, and containing a second positive electrode active material in Fig. 1 (see paragraphs [0009]-[0010], [0051]).
Zeng further discloses the conductive layer 3 disposed on the first coating layer 2 functions to improve electronic conductivity at the interface between the first coating layer 2 and second coating layer 4 (see paragraph [0021]).
Zeng is silent on the layer disposed on the first coating layer being patterned and an area of the first coating layer on which the patterned layer is disposed being 30% to 80% of a total area of the first coating layer.
However, in the same field of endeavor of positive electrodes with conductive layers (see page 2), Hyun discloses a positive electrode comprising a patterned layer coated in a uniform pattern and a positive active material layer in Figs. 1 and 2a-2c (see pages 2 and 6-7).
Hyun additionally discloses coating a conductive layer thinly in a uniform pattern on the current collector improves the bonding force and electrical conductivity of the positive electrode mixture (see pages 2 and 4-5), i.e. the patterned coating layer can improve electronic conductivity at the interface between layers containing positive active material. As such, a skilled artisan would be motivated to use a patterned conductive layer in the positive electrode of Zeng to further improve the bonding force and electronic conductivity between the two layers that contain positive active material.
Hyun further discloses an area of the patterned layer may be 20 to 80% of the current collector area to stably maintain the bonding between the current collector and the positive electrode mixture while maximally suppressing the reduction in electrical conductivity and not adversely affecting the overall volume of the completed battery (see page 5). In the combined structure of Zeng and Hyun, the conductive layer is located on the first layer and as such would the patterned layer would be 20 to 80% of the total area of the first coating layer. This range substantially overlaps and therefore renders obvious the claimed range of the patterned layer being disposed being 30% to 80% of a total area of the first coating layer.
Therefore, it would have been obvious to a person having ordinary skill in the art before the effective filing date of the instant application to modify the positive electrode disclosed by Zeng wherein an area of the first coating layer on which the patterned layer is disposed is 30% to 80% of a total area of the first coating layer, as disclosed by Hyun, in order to improve the bonding force and electronic conductivity between the two layers that contain positive active material.
Zeng further discloses a material for increasing conductivity is required in the conductive layer in order to achieve an improvement of the interface problem caused by poor electronic conductivity between the layers (see paragraph [0021]).
Zeng is silent on the conductive material comprising one or more selected from the group consisting of graphite; metal fiber; aluminum powder; nickel powder; zinc oxide; potassium titanate; titanium oxide; and polyphenylene derivatives.
However, Hyun discloses graphite, metal fiber, aluminum powder, nickel powder, zinc oxide, potassium titanate, titanium oxide, and polyphenylene derivatives are appropriate conductive materials to use in a battery (see pg. 8).
A skilled artisan would expect the graphite, aluminum powder, nickel powder, zinc oxide, and polyphenylene derivatives to function as conductive materials and increase the conductivity in the conductive layer of Zeng. Furthermore, the selection of a known material, which is based upon its suitability for the intended use, is within the ambit of one of ordinary skill in the art. See In re Leshin, 125 USPQ 416 (CCPA 1960) (see MPEP § 2144.07).
Therefore, it would have been obvious to a person having ordinary skill in the art before the effective filing date of the instant application to modify the positive electrode disclosed by Zeng wherein the conductive material comprises one or more selected from the group consisting of graphite; metal fiber; aluminum powder; nickel powder; zinc oxide; potassium titanate; titanium oxide; and polyphenylene derivatives, as disclosed by Hyun, as these are suitable materials to increase the conductivity of the conductive layer.
Regarding Claim 2, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above).
Zeng is silent on the patterned layer having a dot, mesh, stripe or dendritric surface structure.
However, Hyun discloses the patterned layer may have a dot (island), mesh (honeycomb), or stripe pattern in Figs. 2a-2c (see pages 6-7).
Hyun additionally discloses coating a conductive layer thinly in a uniform pattern improves the bonding force and electrical conductivity of the positive electrode mixture (see pages 2 and 4-5), i.e. the patterned coating layer can improve electronic conductivity at the interface between layers. As such, a skilled artisan would be motivated to use a patterned conductive layer in the positive electrode of Zeng to further improve the bonding force and electronic conductivity between the two layers that contain positive active material.
Therefore, it would have been obvious to a person having ordinary skill in the art before the effective filing date of the instant application to modify the positive electrode disclosed by Zeng wherein the patterned layer has a dot, mesh, or stripe structure, as disclosed by Hyun, in order to improve the bonding force and electronic conductivity between the two layers that contain positive active material.
Regarding Claim 3, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above). Zeng further discloses the first positive electrode active material in the first coating layer accounts for preferably 86-90 wt% of the first coating layer and the mass ratio of the binder to the conductive material ranges from 2-6:1 (see paragraphs [0014]-[0015]). The binder and conductive material would account for the remaining 10-14 wt% of the first coating layer (which a skilled artisan would understand is an equivalent measurement to parts by weight of a binder based on 100 parts by weight) and, based on the disclosed ratios, the amount of binder in the first coating layer would substantially overlap with and therefore render obvious the claimed range of the first coating layer comprising 1 to 10 parts by weight of a binder based on 100 parts by weight of the first coating layer.
Zeng also discloses the second positive electrode active material in the second coating layer accounts for preferably 96-99 wt% of the second coating layer and the mass ratio of the conductive material to the binder ranges from 0.5-2:1 (see paragraphs [0024]-[0025]). The binder and conductive material would account for the remaining 1-4 wt% of the second coating layer (which a skilled artisan would understand is an equivalent measurement to parts by weight of a binder based on 100 parts by weight) and, based on the disclosed ratios, the amount of binder in the second coating layer would substantially overlap with and therefore render obvious the claimed range of the second coating layer comprising 1 to 10 parts by weight of a binder based on 100 parts by weight of the second coating layer.
Zeng additionally discloses the binder in the patterned layer comprises one or more resins selected from the group consisting of a polyvinylidene fluoride-hexafluoropropylene copolymer (PVDF- co-HFP), polyvinylidene fluoride, and polymethyl methacrylate (see paragraph [0030]).
Regarding Claim 4, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above). Zeng further discloses the binder in the patterned layer comprises one or more resins selected from the group consisting of a polyvinylidene fluoride-hexafluoropropylene copolymer (PVDF- co-HFP), polyvinylidene fluoride, polymethyl methacrylate, carboxymethyl cellulose (CMC), tetrafluoroethylene, styrene butadiene rubber (see paragraph [0030]).
Regarding Claim 7, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above). Zeng further discloses the thickness of the conductive layer is 1-5 μm (see paragraph [0019]). A skilled artisan would recognize the thickness of the conductive layer is an equivalent measurement to the height of the conductive layer in a cross-section. This range falls within and therefore anticipates the claimed range of an average height of the patterned layer being 0.5 μm to 50 μm based on the cross-section.
Regarding Claim 8, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above). Zeng further discloses an average thickness of the first coating layer is 1 μm to 10 μm (see paragraph [0013]). This falls within and therefore anticipates the claimed range of an average thickness of the first coating layer being 0.1 μm to 10 μm.
Regarding Claim 9, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above). Zeng further discloses the thickness of the second coating layer is preferably 70-90 μm (which a skilled artisan is capable of designating as SD) and the thickness of the conductive layer is 1-5 μm (which a skilled artisan is capable of designating as PD) (see paragraphs [0019] and [0022]). The ratio between these thicknesses (SD/PD) ranges from 14 to 90. This range falls within and therefore anticipates the claimed range of 6≤SD/PD≤100 wherein, in Equation 1, SD represents an average thickness of the second coating layer, and PD represents an average thickness of the patterned layer.
Regarding Claim 10, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above). Zeng further discloses the first positive electrode active material may comprise lithium iron phosphate (see paragraph [0016]). A skilled artisan would recognize lithium iron phosphate has the formula of LiFePO4, which falls within and therefore anticipates the claimed Chemical Formula 1 of Li1+aFe1-bM1b(PO4-c)Xc wherein, in Chemical Formula 1, M1 is one or more selected from the group consisting of Al, Mg and Ti, X is one or more selected from the group consisting of F, S and N, and a, b and c are −0.5≤a≤+0.5, 0≤b≤0.5, 0≤c≤0.1, respectively.
Regarding Claim 11, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above). Zeng further discloses the second positive electrode active material may comprise lithium cobalt oxide (see paragraph [0023]), which a skilled artisan would recognize has a chemical formula of LiCoO2. This formula falls within and therefore anticipates the claimed Chemical Formula 2 of LiCo1-qM2qO2 wherein, in Chemical Formula 2, M2 is one or more elements selected from the group consisting of W, Cu, Fe, V, Cr, Ti, Zr, Zn, Al, In, Ta, Y, La, Sr, Ga, Sc, Gd, Sm, Ca, Ce, Nb, Mg, B, and Mo, and q is 0≤q≤0.4.
Regarding Claim 12, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above). Zeng further discloses a lithium secondary battery comprising the positive electrode for the lithium secondary battery according to the aforementioned claim 1 (see paragraphs [0002], [0007], and [0051]).
Regarding Claim 13, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above). Zeng further discloses a material for increasing conductivity is required in the conductive layer in order to achieve an improvement of the interface problem caused by poor electronic conductivity between the layers (see paragraph [0021]).
Zeng is silent on the conductive material comprising graphite comprising natural graphite or artificial graphite.
However, Hyun discloses graphite such as natural graphite or artificial graphite are appropriate conductive materials to use in a battery (see pg. 8).
A skilled artisan would expect the natural or artificial graphite to function as a conductive material and increase the conductivity in the conductive layer of Zeng. Furthermore, the selection of a known material, which is based upon its suitability for the intended use, is within the ambit of one of ordinary skill in the art. See In re Leshin, 125 USPQ 416 (CCPA 1960) (see MPEP § 2144.07).
Therefore, it would have been obvious to a person having ordinary skill in the art before the effective filing date of the instant application to modify the positive electrode disclosed by Zeng wherein the conductive material comprises graphite comprising natural graphite or artificial graphite, as disclosed by Hyun, as it is a suitable material to increase the conductivity of the conductive layer.
Claim 6 is rejected under 35 U.S.C. 103 as being unpatentable over Zeng in view of Hyun as applied to claim 1 above, and further in view of Li et al. US-20170092943-A1 (hereinafter referred to as Li).
Regarding Claim 6, modified Zeng discloses the positive electrode for the lithium secondary battery according to claim 1 (see rejection of claim 1 above). Zeng further discloses the high conductivity of the conductive layer can be utilized to improve the interface problem caused by poor electronic conductivity between layers in the positive electrode plate during the cycle process (see paragraph [0021]).
Zeng and Hyun are silent on an amount of the conductive material in the patterned layer being 1 to 50 parts by weight based on 100 parts by weight of the binder.
However, in the same field of endeavor of positive electrodes with multiple layers (see abstract), Li discloses a positive electrode comprising a first coating layer (first active material layer) disposed on one or both surfaces of the current collector and containing a first positive electrode active material; a buffer layer disposed on the first coating layer and having a binder and a conductive material (carbon material) dispersed in the binder; and a second coating layer (second active material layer) disposed on the first coating layer on which the buffer layer is disposed, and containing a second positive electrode active material (see abstract and paragraphs [0011]-[0012], [0030], and [0032]-[0033]). Li further discloses the ratio of the total weight of the carbon material to the total weight of the binder is 1:9~9:1 (see paragraphs [0032]-[0034]).
Li additionally discloses the binder functions to expand at a rising temperature, so as to reduce the thermal runaway (see paragraphs [0033]-[0036]).
Furthermore, with the combined teachings of Zeng disclosing the importance of optimizing the conductivity via a conductive material and Li disclosing the importance of optimizing the safety via the expansion of the binder, the ratio between these materials in the patterned layer is a result effective variable, and the discovery of an optimum value of a known result effective variable, without producing any new or unexpected results, is within the ambit of a person of ordinary skill in the art. See In re Boesch, 205 USPQ 215 (CCPA 1980) (see MPEP § 2144.05, II.). So, a skilled artisan would be able to optimize the ratio disclosed by Li to arrive at an amount of the conductive material in the patterned layer of 1 to 50 parts by weight based on 100 parts by weight of the binder.
Therefore, it would have been obvious to a person having ordinary skill in the art before the effective filing date of the instant application to modify the positive electrode disclosed by Zeng and Hyun wherein an amount of the conductive material in the patterned layer is 1 to 50 parts by weight based on 100 parts by weight of the binder, as disclosed by Li, in order to optimize the effects of conductive material and binder to improve conductivity and safety, respectively.
Conclusion
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/S.L.K./Examiner, Art Unit 1729
/ULA C RUDDOCK/Supervisory Patent Examiner, Art Unit 1729
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