Prosecution Insights
Last updated: April 19, 2026
Application No. 18/019,494

PRODUCTION OF THIOPOLYMERS BY REACTIVE EXTRUSION

Non-Final OA §103
Filed
Feb 03, 2023
Examiner
FANG, SHANE
Art Unit
1766
Tech Center
1700 — Chemical & Materials Engineering
Assignee
Arkema Inc.
OA Round
1 (Non-Final)
76%
Grant Probability
Favorable
1-2
OA Rounds
2y 6m
To Grant
95%
With Interview

Examiner Intelligence

Grants 76% — above average
76%
Career Allow Rate
1136 granted / 1491 resolved
+11.2% vs TC avg
Strong +19% interview lift
Without
With
+19.0%
Interview Lift
resolved cases with interview
Typical timeline
2y 6m
Avg Prosecution
51 currently pending
Career history
1542
Total Applications
across all art units

Statute-Specific Performance

§101
0.4%
-39.6% vs TC avg
§103
43.9%
+3.9% vs TC avg
§102
24.3%
-15.7% vs TC avg
§112
16.5%
-23.5% vs TC avg
Black line = Tech Center average estimate • Based on career data from 1491 resolved cases

Office Action

§103
Notice of Pre-AIA or AIA Status The present application, filed on or after March 16, 2013, is being examined under the first inventor to file provisions of the AIA . DETAILED ACTION All the references cited in the International Search Report have been considered. None is anticipatory or meet the amended claims. The most pertinent of these references have been applied below. The amendment is supported by the original disclosure. Election/Restrictions Applicant’s election with traverse of Group I, Claims 1-16 and 18-19, is acknowledged. All groups are distinct inventions and present a serious burden to the U.S. Patent and Trademark Office based on a proper lack of unity analysis. The traversal is on the ground that the restriction is only proper if the claims are independent or distinct and there would be a serious burden placed on the Examiner if restriction is not required. This is not found persuasive because the issue as to the meaning and intent regarding “independent and distinct” as used in 35 U.S.C 121 and 37 CFR 1.41, which is for national applications, but it is not used for PCT national stage (371) applications. For PCT national stage applications, restriction is based upon unity of invention; restriction of a national stage application does not take into account whether or not the inventions are independent or distinct, and does not take into account burden on the examiner. The applicant argued the special technical feature is not met by prior arts in view of the amendment. The examiner disagrees. The examiner asserts the special technical feature is met by prior arts. See below rejections. Amended claim 13 is directed to an invention that is independent or distinct from the invention originally claimed for the following reasons: claim 13 is drawn to a process further comprising a step in addition to the claimed process of claim 1. The restriction, based on the same rationale of lack of unity, as stated in the previous office action is repeated here as such. Since applicant has received an action on the merits for the originally presented invention, this invention has been constructively elected by original presentation for prosecution on the merits. If, after an office action on an application, the applicant presents claims directed to an invention distinct from and independent of the invention previously claimed, the applicant will be required to restrict the claims to the invention previously claimed if the amendment is entered, subject to reconsideration and review as provided in §1.143 and 1.144. See 37 CFR 1.142(b) and MPEP § 821.03. Accordingly, claim 13 is withdrawn from consideration as being directed to a non-elected invention. To facilitate the prosecution, the examiner withdraws the previous election of species. This restriction is made FINAL. The restriction and election of species as stated in the previous office action are repeated here as such. Claim Rejections - 35 USC § 103 The following is a quotation of 35 U.S.C. 103 which forms the basis for all obviousness rejections set forth in this Office action: A patent for a claimed invention may not be obtained, notwithstanding that the claimed invention is not identically disclosed as set forth in section 102 of this title, if the differences between the claimed invention and the prior art are such that the claimed invention as a whole would have been obvious before the effective filing date of the claimed invention to a person having ordinary skill in the art to which the claimed invention pertains. Patentability shall not be negated by the manner in which the invention was made. Claim(s) 1-16 and 18 is (are) rejected under 35 U.S.C. 103(a) as being unpatentable over Pyun et al. (US 20140199592) in view of Ramanathan et al. (US 20030069362) and evidenced by Blasius et al. (US 20040138381). As to claims 1, 9-11, 15, Pyun (abs., claims, examples, figures) discloses a process of producing polysulfide for mold application (60, 63, 65) via inverse vulcanization (Fig.1, claims 26-30) by polymerizing (Ex.2) of sulfur (0.36g) with vinyl monomers (38) such as divinylbenzene (0.198g). The weight ratio is 1.8:1, falling withing the range of claim 15. Divinylbenzene meets the unsaturated hydrocarbon of claims 9-11. As to claim 3, Pyun (Ex.2) teaches feeding divinylbenzene independently to sulfur. Pyun teaches the copolymer may comprises other comonomers, such as 1,2-diisoperpenyl benzene (Ex.5, claim 18). Pyun is silent on the using the claimed extrusion method. In the same area of endeavor of producing molds (2) using a composition comprising sulfur (11), olefins such as propylene (2, 10, claim 12), and ethylidene norbornene (EPDM, 27), Ramanthan (abs., claims, examples) discloses using an extruder via reactive extrusion (37-40) to produce extrudate from monomers to directly form into molded articles. The reactive extruder is a well-known continuous reactor (meets claim 4) for polymerizing vinyl monomers such as styrene (24, claim 1), as evidenced by Blasius (33-34, 45). As to claim 2, Pyun, Ramanathan, and Blasius do not teach feeding reactants concurrently. However, selection of any order of mixing ingredients is prima facie obvious. In re Gibson, 39 F.2d 975, 5 USPQ 230 (CCPA 1930). As to claims 5 and 12-13, the extruder (44) comprises a barrel having temperature profile of 100-220 °C, and the extruder comprises a screw having a compression ratio of 3:1. As to claims 6-8, Pyun, Ramanathan, and Blasius do not teach a sequence of extruders operated at different temperatures and pressure. However, mere duplication of parts has no patentable significance unless a new and unexpected result is produced. In re Harza, 274 F.2d 669, 124 USPQ 378 (CCPA 1960). See MPEP-2144.04. Furthermore, one of ordinary skill in the art would obviously recognize to use different temperatures and pressure for different reactive extruders to polymerize Pyun’s copolymer comprising different comonomers based on their different reactivity toward sulfur to facilitate the inverse vulcanization. As to claim 14, the extruder may comprise twin screws (47). As to claim 16, Pyun (Fig.2, Ex.2) discloses melting and ring opening sulfur (cyclic S8) before the polymerization. In light of this, one of ordinary skill in the art would obviously recognize to melt sulfur in the extruder via screwing movement that would inherently rotate to pressurize at elevated temperature before injection of Pyon’s divinylbenzene into the barrel for polymerization. As to claim 18, the extruder may comprise different temperature zones (38, 44). Therefore, as to claims 1-16 and 18, it would have been obvious to one of ordinary skill in the art to have modified the process disclosed by Pyun and utilized the extruders in view of Ramanathan and Blasius, because the resultant process would produce polymeric extrudate from monomers to directly form into molded articles via the polymerization in the reactive extruder. Claim(s) 19 is (are) rejected under 35 U.S.C. 103(a) as being unpatentable over Pyun et al. (US 20140199592) in view of Ramanathan et et al. (US 20030069362) and evidenced by Blasius et al. (US 20040138381) in view of James et al. (US 20070129483). Disclosure of Pyun, Ramanathan, and Blasius is adequately set forth in ¶1 and is incorporated herein by reference. They are silent on venting gas during the extrusion. In the same area of endeavor of producing mold (52) via extrusion using a composition comprising sulfur vulcanizing agent (11, 30) and olefins such as ethylidene norbornene (60,19, 27), James (46) discloses introducing vent ports to remove volatiles in the extruder. Therefore, as to claim 19, it would have been obvious to one of ordinary skill in the art to have modified the process disclosed by Pyun, Ramanathan, and Blasius and added vent ports to the extruder in view of James, because the resultant process would yield decreased volatiles. Conclusion Any inquiry concerning this communication or earlier communications from the examiner should be directed to SHANE FANG whose telephone number is (571)270-7378. The examiner can normally be reached on Mon-Thurs. 8am-6pm. The fax phone number for the organization where this application or proceeding is assigned is 571-273-8300. If attempts to reach the examiner by telephone are unsuccessful, the examiner’s supervisor, Randy Gulakowski can be reached on 571.572.1302. Information regarding the status of an application may be obtained from the Patent Application Information Retrieval (PAIR) system. Status information for published applications may be obtained from either Private PAIR or Public PAIR. Status information for unpublished applications is available through Private PAIR only. For more information about the PAIR system, see http://pair-direct.uspto.gov. Should you have questions on access to the Private PAIR system, contact the Electronic Business Center (EBC) at 866-217-9197 (toll-free). If you would like assistance from a USPTO Customer Service Representative or access to the automated information system, call 800-786-9199 (IN USA OR CANADA) or 571-272-1000. /SHANE FANG/Primary Examiner, Art Unit 1766
Read full office action

Prosecution Timeline

Feb 03, 2023
Application Filed
Feb 03, 2023
Response after Non-Final Action
Feb 26, 2026
Non-Final Rejection — §103 (current)

Precedent Cases

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Study what changed to get past this examiner. Based on 5 most recent grants.

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Prosecution Projections

1-2
Expected OA Rounds
76%
Grant Probability
95%
With Interview (+19.0%)
2y 6m
Median Time to Grant
Low
PTA Risk
Based on 1491 resolved cases by this examiner. Grant probability derived from career allow rate.

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