Notice of Pre-AIA or AIA Status
The present application, filed on or after March 16, 2013, is being examined under the first inventor to file provisions of the AIA .
Information Disclosure Statement
The information disclosure statements (IDS) submitted on 3/16/23 and 11/12/25 have been considered by the examiner.
Election/Restrictions
Applicant’s election without traverse of Group II comprising claim 7-14 in the reply filed on 12/29/25 is acknowledged. Claims 1-6 and 15-20 are withdrawn as being directed toward a nonelected invention.
Claim Interpretation
Claim 14 recites the electrode active material is “Li-NMC”, which is defined on page 7 of the specification as “lithium nickel manganese cobalt oxides (Li-NMC)”. Thus, Li-NMC is interpreted to mean lithium nickel manganese cobalt oxide.
Claim Rejections - 35 USC § 102
The following is a quotation of the appropriate paragraphs of 35 U.S.C. 102 that form the basis for the rejections under this section made in this Office action:
A person shall be entitled to a patent unless –
(a)(1) the claimed invention was patented, described in a printed publication, or in public use, on sale, or otherwise available to the public before the effective filing date of the claimed invention.
Claim(s) 7-13 is/are rejected under 35 U.S.C. 102(a)(1) as being anticipated by Heo et al., US 2022/0407181 A1, as evidenced by Wikipedia printout for tert-butyl alcohol.
Heo teaches a first polymer solution and a second polymer solution that once prepared are mixed to prepare a third polymer solution (mixture). The first polymer solution is prepared by dissolving a first binder resin (first polymer) in a first solvent, while the second polymer solution is prepared by dissolving a second binder resin (second polymer) in a second solvent. The first solvent can dissolve the first binder resin, and is a non-solvent for the second binder resin. The first solvent may be one capable of dissolving the first binder resin. In addition, the first solvent is a non-solvent for the second binder resin. Non-limiting examples of the first solvent include any one selected from ketone solvents, such as acetone, methyl ethyl ketone (MEK), methyl isobutyl ketone (MIBK), or the like, or a mixture of two or more of them. The second solvent can dissolve the second binder resin, and is a non-solvent for the first binder resin. The second solvent may be one capable of dissolving the second binder resin. In addition, the second solvent is a non-solvent for the first binder resin. Non-limiting examples of the second solvent include at least one selected from water, methanol, ethanol, propyl alcohol, butyl alcohol, butanediol, ethylene glycol, propylene glycol and tripropylene glycol [0071-0074]. The second binder resin may comprise polyvinyl pyrrolidone (PVP) [claim 1 of Heo]. The first binder resin comprises a fluorinated binder resin such as polyvinylidene fluoride hexafluoropropylene (a polypropylene containing polymer) [claim 2 of Heo].
Thus, the claims are anticipated. The first solvent, acetone (about 39 kPa @25°C) or MEK (about 13 kPa @25°C), of Heo inherently has a higher vaporization pressure than the second solvent, butyl alcohol (about 1 kPa @25°C), of Heo. Similarly, the second solvent, butyl alcohol (about 25°C), of Heo inherently has a greater freezing point than the first solvent, acetone (about -95°C) or MEK (about -86°C), of Heo.
Regarding claim 10, butyl alcohol refers to a general category of alcohols with the formula C4H9OH, which includes butanol, isobutanol and t-butanol. Tert-butyl alcohol is a specific type of the butyl alcohol disclosed by Heo. This is evidenced by the below citation/tert-butyl alcohol Wikipedia definition.
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Regarding claim 13, the polymer solution may comprise inorganic particles such as those disclosed at [0047-0048] of Heo. The inorganic particles may be Li3PO4, an active material. The inorganic particles may be lithium titanium phosphate, an active material. The broad limitation “an electrode support” of claim 13 has been given the broadest reasonable interpretation. The particles disclosed at [0047] or heat-absorbing material disclosed at [0050] may be considered the “electrode support”.
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Claim(s) 7-9, 11 and 13-14 are is/are rejected under 35 U.S.C. 102(a)(1) as being anticipated by Tanaka et al., US 2020/0295346 A1.
Tanaka teaches a dispersion (composition comprising a mixture) including an electrode active material, a binder formed of polyvinylidene fluoride (PVdF) (first polymer of present claims), a first solvent (second solvent of present claims) in which the polyvinylidene fluoride (PVdF) is not dissolved, and a second solvent (first solvent of present claims) in which the polyvinylidene fluoride (PVdF) can be dissolved [abstract]. Other binders such as polypropylene and ethylene-propylene block copolymer (second polymer of present claims) may be contained in the dispersion [0150]. Examples of the first solvent include ethylene carbonate (EC), propylene carbonate (PC), diethyl carbonate (DEC), and the like. The first solvent is a solvent having low volatility (that is, a low vapor pressure) . Specifically, the vapor pressure of the first solvent at 25°C is preferably less than 3,200 Pa, and more preferably less than 1,000 Pa [0179-0180]. The second solvent is preferably a solvent having high volatility from the viewpoint of easiness of removal, and examples thereof include dimethyl carbonate (dimethyl carbonate, DMC), acetone, ethanol, and the like. Among those, dimethyl carbonate is particularly preferable from the viewpoint of a low water content in the solvent. The second solvent (first solvent of present claims) is a solvent having higher volatility than the first solvent. In other words, the second solvent is a solvent whose vapor pressure is higher than that of the first solvent. Specifically, the vapor pressure of the second solvent at 25°C is more preferably 3,200 Pa or more, and still more preferably 6,000 Pa or more [0185-0186]. The freezing point of acetone (first solvent of present claims) is about -95°C. The second solvent is a solvent in which polyvinylidene fluoride (PVdF) can be dissolved [0184]. The first solvent is a solvent in which polyvinylidene fluoride (PVdF) is not dissolved [0178].
Thus, the claims are anticipated. Note the first solvent of Tanaka corresponds to the second solvent of the present claims and the second solvent of Tanaka corresponds to the first solvent of the present claims. Polypropylene is inherently not soluble in acetone. Regarding claims 13-14, the electrode active material may be lithium nickel manganese cobalt oxide [0038]. The conductive aid may be carbon black [0051]. The dispersion may include the electrode active material and the conductive aid [0189].
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Conclusion
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/TRACY M DOVE/ Primary Examiner, Art Unit 1725