DETAILED ACTION
Notice of Pre-AIA or AIA Status
The present application, filed on or after March 16, 2013, is being examined under the first inventor to file provisions of the AIA .
Continued Examination Under 37 CFR 1.114
A request for continued examination under 37 CFR 1.114, including the fee set forth in 37 CFR 1.17(e), was filed in this application after final rejection. Since this application is eligible for continued examination under 37 CFR 1.114, and the fee set forth in 37 CFR 1.17(e) has been timely paid, the finality of the previous Office action has been withdrawn pursuant to 37 CFR 1.114. Applicant's submission filed on 11/04/2025 has been entered.
Response to Amendment
The amendment of 10/21/2025 has been entered.
Disposition of claims:
Claims 1-6 and 8-20 are pending.
Claim 1 has been amended.
The amendment of claim 1 has overcome the rejections of claims 1-6 and 8-20 under 35 U.S.C. 103 as being unpatentable over Niboshi et al. (US 2020/0388780 A1, hereafter Niboshi) in view of Hatakeyama et al. (“Ultrapure Blue Thermally Activated Delayed Fluorescence Molecules: Efficient HOMO–LUMO separation by the Multiple Resonance Effect”, Adv. Mater. 2016, vol. 28, page 2777-2781, hereafter Hatakeyama) set forth in the last Office Action. The rejection has been withdrawn.
Response to Arguments
Applicant’s arguments see page 13-15 of the reply filed 10/21/2025 regarding the rejections of claims 1-6 and 8-20 under 35 U.S.C. 103 as being unpatentable over Niboshi/Hatakeyama set forth in the Office Action of 05/30/2025 have been considered.
Applicant argues that the amended claim 1 and its dependent claims would not have been obvious over Niboshi and Hatakeyama.
The cited rejections refer to the Light emitting device of Niboshi as modified by Hatakeyama (sections 38 through 41 of the last Office Action) a first electrode (anode), a hole transport layer, a second emission layer (green phosphorescent emission layer) comprising TPD as a host and Ir(ppy)2(acac) as a dopant, a first emission layer (a combined layer of a blue phosphorescence emission layer and a blue fluorescence emission layer) comprising TPD as a host and DABNA-2 as a dopant, an electron transport layer, and a second electrode (cathode).
The first emission layer of the device is a combination of two sublayers (i.e. a blue phosphorescence emission layer and a blue fluorescence emission layer). However, the amended claims require each of the first and second emission layers to be a single-layered structure consisting of a single layer. Thus, the Light emitting device of Niboshi as modified by Hatakeyama does not read on the limitation of the amended claims. The rejections are withdrawn.
Specification
The disclosure is objected to because of the following informalities:
in paragraph [0102] on pages 30-31, some of structural formulas including at least FD22 to FD33 have poor image resolution. It is suggested to improve the resolution of the images.
in paragraph [0121] on page 36, some of structural formulas including at least the first to the seventh compounds have poor image resolution. It is suggested to improve the resolution of the images.
Appropriate correction is required.
Claim Rejections - 35 USC § 103
In the event the determination of the status of the application as subject to AIA 35 U.S.C. 102 and 103 (or as subject to pre-AIA 35 U.S.C. 102 and 103) is incorrect, any correction of the statutory basis for the rejection will not be considered a new ground of rejection if the prior art relied upon, and the rationale supporting the rejection, would be the same under either status.
The text of those sections of Title 35, U.S. Code not included in this action can be found in a prior Office action.
The factual inquiries for establishing a background for determining obviousness under 35 U.S.C. 103 are summarized as follows:
1. Determining the scope and contents of the prior art.
2. Ascertaining the differences between the prior art and the claims at issue.
3. Resolving the level of ordinary skill in the pertinent art.
4. Considering objective evidence present in the application indicating obviousness or nonobviousness.
This application currently names joint inventors. In considering patentability of the claims the examiner presumes that the subject matter of the various claims was commonly owned as of the effective filing date of the claimed invention(s) absent any evidence to the contrary. Applicant is advised of the obligation under 37 CFR 1.56 to point out the inventor and effective filing dates of each claim that was not commonly owned as of the effective filing date of the later invention in order for the examiner to consider the applicability of 35 U.S.C. 102(b)(2)(C) for any potential 35 U.S.C. 102(a)(2) prior art against the later invention.
Claims 1-6 and 8-20 are rejected under 35 U.S.C. 103 as being unpatentable over Liping et al. (US 2014/0167014 A1, hereafter Liping) in view of Hatakeyama et al. (“Ultrapure Blue Thermally Activated Delayed Fluorescence Molecules: Efficient HOMO–LUMO separation by the Multiple Resonance Effect”, Adv. Mater. 2016, vol. 28, page 2777-2781, hereafter Hatakeyama), as evidenced by Lai et al. (US 2014/0070194 A1, hereafter Lai), Lepeltier et al. (“Red phosphorescent organic light-emitting diodes(PhOLEDs) based on a heteroleptic cyclometalated Iridium(III) complex”, J. Luminescence 2013, vol. 143, page 145-149, hereafter Lepeltier), Jeong et al. (“Efficient deep-blue emitters based on triphenylamine-linked benzimidazole derivatives for nondoped fluorescent organic light-emitting diodes”, Org. Elec. 2013, vol. 14, page 2497-2504, hereafter Jeong).
Regarding claims 1-6 and 8-17, Liping discloses a light emitting device comprising an anode, a florescent blue emissive layer, a phosphorescent red emissive layer contacting to the fluorescent blue emissive layer, and a cathode ([0003]-[0004]).
Liping exemplifies a device comprising a first electrode, a hole transport layer, a fluorescent blue emissive layer (BE-3 as a blue fluorescent emitter and Host-1 as a host) and a phosphorescent red emissive layer (Ir(piq)2acac as a red phosphorescent emitter and Host-1 as a host), an electron transport layer, and a second electrode (Example 1 in [0068]-[0071], Fig. 3).
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Liping teaches the T1 energy of the compound Host-1 being 2.36 eV (Table 1).
Liping does not disclose a specific light emitting device comprising a boron-containing polycyclic compound as the blue fluorescent emitter; however, Liping does teach that any suitable blue fluorescent emitter can be used ([0022]).
Hatakeyama discloses a thermally activated delayed fluorescent (TADF) compound (DABNA-2) used as the blue emitter of a light emitting device (page 2779, col. 2, and Figs 3-4).
Hatakeyama teaches that the compound DABNA-2 provides ultrapure blue light, high quantum efficiency, excellent color purity (page 2780, col. 2, last paragraph).
At the time the invention was effectively filed, it would have been obvious to one of ordinary skill in the art to have modified the light emitting device of Liping by substituting the blue fluorescent emitter with DABNA-2, as taught by Liping and Hatakeyama.
The motivation of doing so would have been to provides ultrapure blue light, high quantum efficiency, and excellent color purity based on the teaching of Hatakeyama.
Furthermore, the modification would have been a combination of prior art elements according to known material to achieve predictable results. See MPEP 2143(I)(A). The substitution of blue fluorescent emitters in the blue fluorescent emissive layer would have been one known element for another known element and would have led to predictable results. See MPEP 2143(I)(B).
The modification provides Light emitting device of Liping as modified by Hatakeyama comprising a first electrode (anode), a hole transport layer, a blue fluorescence emission layer (Host-1 as a host, DABNA-2 as a dopant), a red phosphorescent emission layer (Host-1 as a host, Ir(piq)2acac as a dopant), an electron transport layer, and a second electrode (cathode).
The Light emitting device of Liping as modified by Hatakeyama is equated with a light emitting device comprising a first electrode (anode), a hole transport layer, a first emission layer (a first host (Host-1) and a first dopant (DABNA-2)), a second emission layer (a second host (Host-1) and a second dopant (Ir(piq)2acac)), an electron transport layer, and a second electrode (cathode).
The Light emitting device of Liping as modified by Hatakeyama reads on the claimed limitations above but fails to teach that the properties 1) to 11) of the device:
1) a triplet energy level of the first host is lower than a triplet energy level of the first dopant, and a triplet energy level of the second host is higher than a triplet energy level of the second 1s dopant (claim 1),
2) a difference between a triplet energy level of the first host and a triplet energy level of the first dopant is in a range of about 0.1 eV to about 0.4 eV (claim 2),
3) a singlet energy level of the first host is higher than a singlet energy level of the first dopant (claim 3),
5) a difference between a triplet energy level of the second host and a triplet energy level of the second dopant is in a range of 3 about 0.05 eV to about 0.3 eV (claim 5),
6) a triplet energy level of the first dopant is higher than a triplet energy level of the second dopant (claim 6), and
7) a difference between a singlet energy level and a triplet energy level of the first dopant is in a range of about 0 eV to about 0.2 eV (claim 1),
8) the first emission layer is configured to emit a first color light, the second emission layer is configured to emit a second color light, and the first color light is different from the second color light (claim 13),
9) a maximum emission wavelength of the first color light is shorter than a maximum emission wavelength of the second color light (claim 14),
10) the first color light is blue light or green light, and the second color light is green light or red light (claim 15), and
11) the light-emitting device is configured to emit a maximum emission wavelength in a range of about 430 nm to about 540 nm or about 500 nm to about 620 nm (claim 16).
It is reasonable to presume that the Light emitting device of Liping as modified by Hatakeyama inherently possesses the properties 1) to 11) above.
Support for said presumption is found in the use of like materials which result in the claimed property.
Liping teaches the T1 energy of Host-1 is 2.36 eV (Table 1).
The instant specification states that S1 and T1 energies of DABNA-2 are each 2.61 eV, and 2.47 eV.
Lai evidences the T1 energy of Ir(piq)2acac is 2.1 eV ([0039]).
Hatakeyama evidences the peak wavelength of DABNA-2 is 469 nm (Table 1).
Lepeltier evidences the peak wavelength of the EL spectrum of Ir(piq)2acac is around 620 nm (Fig. 4).
Regarding the S1 energy of the Host-1 of Liping, Jeong teaches the difference between S1 and T1 states of a similar compound being 0.44 eV (compound T1B in Fig. 1, page 2502, col. 1, line 1). Thus, the difference between S1 and T1 of the Host-1 of Liping is presumed to be 0.44 eV, and the S1 energy of Host-1 of Liping is presumed to be 2.80 eV.
Therefore the Light emitting device of Liping as modified by Hatakeyama inherently possesses all the properties 1) to 11).
The Light emitting device of Liping as modified by Hatakeyama meet the limitation of claims 1-6 and 8-17.
The burden is upon the Applicant to prove otherwise. In re Fitzgerald 205 USPQ 594. In addition, the presently claimed properties would obviously have been present once Light emitting device of Liping as modified by Hatakeyama is provided. Note In re Best, 195 USPQ at 433, footnote 4 (CCPA 1977). Reliance upon inherency is not improper even though the rejection is based on Section 103 instead of 102. In re Skoner, et al. (CCPA) 186 USPQ 80.
Claims 18-20 are rejected under 35 U.S.C. 103 as being unpatentable over Liping et al. (US 2014/0167014 A1) in view of Hatakeyama et al. (“Ultrapure Blue Thermally Activated Delayed Fluorescence Molecules: Efficient HOMO–LUMO separation by the Multiple Resonance Effect”, Adv. Mater. 2016, vol. 28, page 2777-2781) as applied to claims 1-6 and 8-20 above, further in view of Karri et al. (US 2023/0006169 A1, hereafter Karri).
Regarding claims 18-20, the Light emitting device of Liping as modified by Hatakeyama reads on all the features of claim 1 as outlined above.
The device comprises a first electrode (anode), a hole transport layer, a first emission layer (a first host (Host-1) and a first dopant (DABNA-2)), a second emission layer (a second host (Host-1) and a second dopant (Ir(piq)2acac)), an electron transport layer, and a second electrode (cathode).
Liping in view of Hatakeyama does not disclose a specific electronic apparatus comprising the Light emitting device of Liping as modified by Hatakeyama; however, Liping does teach that a light emitting device can be applied to a display device.
Karri teach an electronic apparatus (AMOLED display in [0045], 300 in Fig. 3) comprises a source electrode, a drain electrode, and a thin-film transistor that comprises an active layer (340), wherein the first electrode (336) of a light-emitting device (335) is electrically connected to the source of the drain electrode of the thin-film transistor, and the electronic apparatus further comprises a functional layer comprising a touchscreen layer (“touch sensor layer”, 320).
At the time the invention was effectively filed, it would have been obvious to one of ordinary skill in the art to have modified the Light emitting device of Liping as modified by Hatakeyama by incorporating it into an electronic apparatus comprising the light emitting device, a touch screen layer and a thin film transistor containing a source electrode, a drain electrode and an active layer, wherein the first electrode of the light emitting device is electrically connected to the source electrode or the drain electrode of the thin-film transistor, as taught by Liping and Karri.
The motivation of doing so would have been to provide AMOLED display panel, based on the teaching of Karri.
Furthermore, the modification would have been a combination of prior art elements according to known material to achieve predictable results. See MPEP 2143(I)(A). The substitution of light emitting devices in an AMOLED device would have been one known element for another known element and would have led to predictable results. See MPEP 2143(I)(B).
The modification provides an electronic apparatus comprising the light emitting device of Liping as modified by Hatakeyama, a touch screen layer and a thin film transistor containing a source electrode, a drain electrode and an active layer, wherein the first electrode of the light emitting device is electrically connected to the source electrode or the drain electrode of the thin-film transistor.
Conclusion
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/SEOKMIN JEON/Primary Examiner, Art Unit 1786