DETAILED ACTION
Notice of Pre-AIA or AIA Status
The present application, filed on or after March 16, 2013, is being examined under the first inventor to file provisions of the AIA .
Claim Rejections - 35 USC § 103
The following is a quotation of 35 U.S.C. 103 which forms the basis for all obviousness rejections set forth in this Office action:
A patent for a claimed invention may not be obtained, notwithstanding that the claimed invention is not identically disclosed as set forth in section 102, if the differences between the claimed invention and the prior art are such that the claimed invention as a whole would have been obvious before the effective filing date of the claimed invention to a person having ordinary skill in the art to which the claimed invention pertains. Patentability shall not be negated by the manner in which the invention was made.
The factual inquiries for establishing a background for determining obviousness under 35 U.S.C. 103 are summarized as follows:
1. Determining the scope and contents of the prior art.
2. Ascertaining the differences between the prior art and the claims at issue.
3. Resolving the level of ordinary skill in the pertinent art.
4. Considering objective evidence present in the application indicating obviousness or nonobviousness.
This application currently names joint inventors. In considering patentability of the claims the examiner presumes that the subject matter of the various claims was commonly owned as of the effective filing date of the claimed invention(s) absent any evidence to the contrary. Applicant is advised of the obligation under 37 CFR 1.56 to point out the inventor and effective filing dates of each claim that was not commonly owned as of the effective filing date of the later invention in order for the examiner to consider the applicability of 35 U.S.C. 102(b)(2)(C) for any potential 35 U.S.C. 102(a)(2) prior art against the later invention.
Claims 1-4, 7-12, and 14-19 are rejected under 35 U.S.C. 103 as being unpatentable over Lee et al. (US 2017/0047527 A1, hereafter Lee).
Regarding claims 1-4, 7-12, and 14-19, Lee discloses a light emitting element comprising a first electrode (anode), an emission layer, and a second electrode (cathode), wherein the emission layer comprises a first host compound of Formula 1 and a second host compound of Formula 2 ([0008]).
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Lee teaches the structure of a light emitting element comprising a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, a second host, Compound D-96 as a dopant), an electron transport layer, an electron injection layer, and a second electrode (Example 3-2 in Table 2, [0056]), wherein the compound D-96 is a red phosphorescent emitter.
The second host does not read on the limitation of Applicant’s Formula 1 of the instant claims; however, Lee does teach Compound H2-78 as the second host ([0036]).
At the time the invention was effectively filed, it would have been obvious to one of ordinary skill in the art to have modified the light emitting element of Lee by substituting the second host compound with Compound H2-78, as taught by Lee.
The modification would have been a combination of prior art elements according to known material to achieve predictable results. See MPEP 2143(I)(A). The substitution of the second host compounds of Formula 2 of Lee in the OLED of Lee would have been one known element for another known element and would have led to predictable results. See MPEP 2143(I)(B).
The modification provides Modified light emitting element of Lee comprising a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound H2-78 as a second host, Compound D-96 as a dopant), an electron transport layer, an electron injection layer, and a second electrode.
It should be noted that the Compound H2-78 of Lee does not have a silyl group of Formula 2; however, the compound reads on all the limitations of Applicant’s Formula 1, because the claims allow variables a through f to be zero. That is, the claimed compound of Formula 1 does not require a silyl group of Formula 2 as the substituent.
The Compound H2-78 reads on all the limitations of claims 14-19.
The Modified light emitting element of Lee reads on all the limitations of claims 1-4 and 7-12.
Claim 5 is rejected under 35 U.S.C. 103 as being unpatentable over Lee et al. (US 2017/0047527 A1) as applied to claims 1-4, 7-12, and 14-19 above, further in view of Seo et al. (US 2002/0121860 A1, hereafter Seo).
Regarding claim 5, the Modified light emitting element of Lee reads on all the features of claim 1 as outlined above.
The device comprises a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound H2-78 as a second host, Compound D-96 as a dopant), an electron transport layer, an electron injection layer, and a second electrode.
The device does not comprises an electron transport layer comprising the Compound H2-78 of Lee.
Seo teaches that a mixed layer between two neighboring organic layers of a light emitting element (“organic light-emitting device”) contains both the neighboring organic layer materials (“mixed layer” (105) in Fig. 1B; [0050]; “2nd mixed region” between “light emitting region” and “electron transporting region” in Fig. 19).
Seo teaches that by introducing a mixed layer in-between two neighboring organic layers (device structure of Fig. 1B), the energy barrier is lowered and more carriers can be injected ([0054]).
At the time the invention was effectively filed, it would have been obvious to one of ordinary skill in the art to have modified the Modified light emitting element of Lee by incorporating a mixed layer between the electron transport layer and the emission layer, as taught by Seo.
The motivation of doing so would provide the organic optoelectronic device with lowered energy barrier and improved carrier injection, based on the teaching of Seo.
Furthermore, the modification would have been a combination of prior art elements according to known material to achieve predictable results. See MPEP 2143(I)(A).
The modification provides Light emitting element of Lee as modified by Seo comprising a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound H2-78 as a second host, Compound D-96 as a dopant), a mixed layer containing Compound H2-78 of Lee, an electron transport layer, an electron injection layer, and a second electrode, wherein the mixed layer is equated with an electron transport layer because the layer can transport electrons.
Claim 6 is rejected under 35 U.S.C. 103 as being unpatentable over Lee et al. (US 2017/0047527 A1) as applied to claims 1-4, 7-12, and 14-19 above, further in view of Ossila (Material information of FIrpic from Ossila, web page address: https://www.ossila.com/products/firpic, hereafter Ossila).
Regarding claim 6, the Modified light emitting element of Lee reads on all the features of claim 1 as outlined above.
The device comprises a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound H2-78 as a second host, Compound D-96 as a dopant), an electron transport layer, an electron injection layer, and a second electrode.
The device emits red light and does not emit white light; however, Lee does teach that a blue emitter can be included in the emission layer such that the light emitting device can emit white light ([0047]).
Ossila teaches that FIrpic is commercially available and provides sky blue emission with high efficiency and peak emission wavelength of 468 nm (page 2)
At the time the invention was effectively filed, it would have been obvious to one of ordinary skill in the art to have modified the Modified light emitting element of Lee by incorporating a blue light emitting compound FIrpic in the emission layer of the device as taught by Lee and Ossila.
The motivation of doing so would have been to provide commercial availability, sky blue emission with high efficiency, based on the teaching of Ossila.
Furthermore, the modification would have been a combination of prior art elements according to known material to achieve predictable results. See MPEP 2143(I)(A).
The modification provides light emitting element of Lee as modified by Ossila comprising a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound H2-78 as a second host, Compound D-96 as a dopant, and FIrpic as a dopant), an electron transport layer, an electron injection layer, and a second electrode, wherein the device emits a portion of light having peak emission wavelength of 468 nm.
Claims 1-4 and 7-20 are rejected under 35 U.S.C. 103 as being unpatentable over Lee et al. (US 2017/0047527 A1) in view of Yun et al. (“Triplet Exciton Upconverting Blue Exciplex Host for Deep Blue Phosphors”, Chem. Eur. J. 2021, vol. 27, page 12642-12648, hereafter Yun).
Regarding claims 1-4 and 7-20, Lee discloses a light emitting element comprising a first electrode (anode), an emission layer, and a second electrode (cathode), wherein the emission layer comprises a first host compound of Formula 1 and a second host compound of Formula 2 ([0008]).
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Lee teaches the structure of a light emitting element comprising a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, a second host, Compound D-96 as a dopant), an electron transport layer, an electron injection layer, and a second electrode (Example 3-2 in Table 2, [0056]), wherein the compound D-96 is a red phosphorescent emitter.
The second host does not read on the limitation of Applicant’s Formula 1 of the instant claims; however, Lee does teach Compound H2-78 as the second host ([0036]).
At the time the invention was effectively filed, it would have been obvious to one of ordinary skill in the art to have modified the light emitting element of Lee by substituting the second host compound with Compound H2-78, as taught by Lee.
The modification would have been a combination of prior art elements according to known material to achieve predictable results. See MPEP 2143(I)(A). The substitution of the second host compounds of Formula 2 of Lee in the OLED of Lee would have been one known element for another known element and would have led to predictable results. See MPEP 2143(I)(B).
The modification provides Modified light emitting element of Lee comprising a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound H2-78 as a second host, Compound D-96 as a dopant), an electron transport layer, an electron injection layer, and a second electrode.
The Compound H2-78 of Lee does not have a triphenyl silyl group substituted to the phenyl substituted to the triazinyl group (i.e. the positions pointed by arrows in the figure above). However, Lee does teach that the phenyl group substituted to the triazinyl group can be further substituted by a triphenyl silyl group (see examples including at least compound H2-10 in [0036]).
Yun discloses a compound used for a light emitting element (Abstract), wherein the compound comprises a diphenyl substituted triazinyl structure; and the diphenyl groups are each substituted by a triphenyl silyl group (Scheme 1; see the parts enclosed by a dashed circle in the figure below).
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Yun teaches that the triphenylsilyl group surrounds the triazine core and prevents intermolecular packing and provides high triplet energy (page 12643, col. 1, par. 1).
At the time the invention was effectively filed, it would have been obvious to one of ordinary skill in the art to have modified the Compound H2-78 of Lee by substituting each of the phenyl groups substituted to the triazinyl group with a triphenyl silyl group, as taught by Lee and Yun.
The motivation of doing so would have been to surround the triazine core, prevent intermolecular packing and provide high triplet energy, based on the teaching of Yun.
Furthermore, the modification would have been a combination of prior art elements according to known material to achieve predictable results. See MPEP 2143(I)(A). The substitution of exemplified substituents from hydrogen to triphenyl silyl group in the compound of Formula 2 of Lee would have been one known element for another known element and would have led to predictable results. See MPEP 2143(I)(B).
The modification provides Compound of Lee as modified by Yun which has identical structure as Applicant’s Compound 1 of the instant claims, meeting all the limitations of claims 14-20.
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The modification also provides Light emitting element of Lee as modified by Yun comprising a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound Lee as modified by Yun as a second host, Compound D-96 as a dopant), an electron transport layer, an electron injection layer, and a second electrode, meeting all the limitations of claims 1-4 and 7-13.
Claim 5 is rejected under 35 U.S.C. 103 as being unpatentable over Lee et al. (US 2017/0047527 A1) in view of Yun et al. (“Triplet Exciton Upconverting Blue Exciplex Host for Deep Blue Phosphors”, Chem. Eur. J. 2021, vol. 27, page 12642-12648), as applied to claims 1-4 and 7-20 above, further in view of Seo et al. (US 2002/0121860 A1).
Regarding claim 5, the Light emitting element of Lee as modified by Yun reads on all the features of claim 1 as outlined above.
The device comprises a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound Lee as modified by Yun as a second host, Compound D-96 as a dopant), an electron transport layer, an electron injection layer, and a second electrode.
The device does not comprises an electron transport layer comprising the Compound of Lee as modified by Yun.
Seo teaches that a mixed layer between two neighboring organic layers of a light emitting element (“organic light-emitting device”) contains both the neighboring organic layer materials (“mixed layer” (105) in Fig. 1B; [0050]; “2nd mixed region” between “light emitting region” and “electron transporting region” in Fig. 19).
Seo teaches that by introducing a mixed layer in-between two neighboring organic layers (device structure of Fig. 1B), the energy barrier is lowered and more carriers can be injected ([0054]).
At the time the invention was effectively filed, it would have been obvious to one of ordinary skill in the art to have modified the Modified light emitting element of Lee by incorporating a mixed layer between the electron transport layer and the emission layer, as taught by Seo.
The motivation of doing so would provide the organic optoelectronic device with lowered energy barrier and improved carrier injection, based on the teaching of Seo.
Furthermore, the modification would have been a combination of prior art elements according to known material to achieve predictable results. See MPEP 2143(I)(A).
The modification provides Light emitting element of Lee as modified by Yun and Seo comprising a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound of Lee as modified by Yun as a second host, Compound D-96 as a dopant), a mixed layer containing the Compound of Lee as modified by Yun, an electron transport layer, an electron injection layer, and a second electrode, wherein the mixed layer is equated with an electron transport layer because the layer can transport electrons.
Claim 6 is rejected under 35 U.S.C. 103 as being unpatentable over Lee et al. (US 2017/0047527 A1) in view of Yun et al. (“Triplet Exciton Upconverting Blue Exciplex Host for Deep Blue Phosphors”, Chem. Eur. J. 2021, vol. 27, page 12642-12648), as applied to claims 1-4 and 7-20 above, further in view of Ossila (Material information of FIrpic from Ossila, web page address: https://www.ossila.com/products/firpic).
Regarding claim 6, the Light emitting element of Lee as modified by Yun reads on all the features of claim 1 as outlined above.
The device comprises a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound of Lee as modified by Yun as a second host, Compound D-96 as a dopant), an electron transport layer, an electron injection layer, and a second electrode.
The device emits red light and does not emit white light; however, Lee does teach that a blue emitter can be included in the emission layer such that the light emitting device can emit white light ([0047]).
Ossila teaches that FIrpic is commercially available and provides sky blue emission with high efficiency and peak emission wavelength of 468 nm (page 2)
At the time the invention was effectively filed, it would have been obvious to one of ordinary skill in the art to have modified the Modified light emitting element of Lee by incorporating a blue light emitting compound FIrpic in the emission layer of the device as taught by Lee and Ossila.
The motivation of doing so would have been to provide commercial availability, sky blue emission with high efficiency, based on the teaching of Ossila.
Furthermore, the modification would have been a combination of prior art elements according to known material to achieve predictable results. See MPEP 2143(I)(A).
The modification provides light emitting element of Lee as modified by Yun and Ossila comprising a first electrode, a hole injection layer, an emission layer (Compound C-1 as a first host, Compound of Lee as modified by Yun as a second host, Compound D-96 as a dopant, and FIrpic as a dopant), an electron transport layer, an electron injection layer, and a second electrode, wherein the device emits a portion of light having peak emission wavelength of 468 nm.
Conclusion
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/SEOKMIN JEON/Primary Examiner, Art Unit 1786