DETAILED ACTION
Notice of Pre-AIA or AIA Status
The present application is being examined under the pre-AIA first to invent provisions.
Response to Arguments
Applicant’s arguments, Pre-Appeal Brief Review, see Issue 1, pages 3-4, regarding the barrier layer (BI1b), filed July 13, 2026, with respect to the rejection of claim 1 under 35 USC § 103 have been fully considered and are persuasive. Therefore, the rejection has been withdrawn. However, upon further consideration, a new ground(s) of rejection is made in view of different interpretation of the previously applied references.
Status of the Claims
Species 1, as shown in FIG. 3, is elected.
Claims 1-44 are pending.
Action on merits of the Elected Species 1, claims 1-44 follows.
Claim Rejections - 35 USC § 103
The text of those sections of Title 35, U.S. Code not included in this action can be found in a prior Office action.
Claims 1-44 are rejected under pre-AIA 35 U.S.C. 103(a) as being unpatentable over HOTTA et al. (US. Pub. No. 2007/0020829) in view of NOGUCHI et al. (US. Pub. No. 2004/0227242) both of record.
With respect to claim 1, HOTTA teaches a semiconductor device substantially as claimed including:
a semiconductor substrate (1);
a MISFET (9) formed on the semiconductor substrate (1);
5a contact interlayer insulating film (14) covering the MISFET (Q) formed on the semiconductor substrate (1);
a first plug (16) formed in the contact interlayer insulating film (14) and electrically connected to the MISFET (Q);
a first interlayer insulating film (17) formed on the contact 10interlayer insulating film (14);
a first layer wiring (19) formed in the first interlayer insulating film (17) and electrically connected to the first plug (16);
a barrier insulating film formed on the first interlayer insulating film (17) and the first layer wiring (19), the barrier insulating film formed of i) a SiCN film (21) and ii) a SiCO film (22) formed on the SiCN film (21);
a second interlayer insulating film (23) formed on the barrier insulating film such that the second interlayer insulating film (23) directly contact the barrier insulating film;
15a second plug (33 plug) formed in the second interlayer insulating film (23) and electrically connected to the first layer wiring (19); and
a second layer wiring (33 wiring) formed in the second interlayer insulating film (23) and electrically connected to the second plug (33 plug),
wherein the contact interlayer insulating film (14) is formed of 20a high-dielectric-constant film (TEOS) having the highest dielectric constant among the contact interlayer insulating film (14), the first interlayer insulating film (17) and the second interlayer insulating film (23),
wherein the second interlayer insulating film (23) is formed of a 25low-dielectric-constant film having the low dielectric constant among the contact interlayer insulating film (14), the first interlayer insulating film (17) and the second interlayer insulating film (23), and
- 108 -wherein the first interlayer insulating film (17) is formed of a middle-dielectric-constant film having dielectric constant lower than that of the contact interlayer insulating film (14),
wherein a dielectric constant of the high-dielectric-constant film (14) is larger than or equal to 3.5,
wherein a dielectric constant of the middle-dielectric-constant film (17) is larger than or equal to 2.8 and smaller than 3.5, and
wherein a dielectric constant of the low-dielectric-constant film (23) is smaller than 2.8. (See FIG. 10).
Thus, HOTTA is shown to teach all the features of the claim with the exception of explicitly disclosing the second interlayer insulating film being formed of a 25low-dielectric-constant film having the lowest dielectric constant among the contact interlayer insulating film, the first interlayer insulating film and the second interlayer insulating film.
However, NOGUCHI HOTTA teaches a semiconductor device including:
a first interlayer insulating film (15) formed on contact 10interlayer insulating film (11);
a barrier insulating film formed on the first interlayer insulating film (15); and
a second interlayer insulating film (23) formed on the barrier insulating film such that the second interlayer insulating film (23) directly contact the barrier insulating film;
wherein the contact interlayer insulating film (11) is formed of 20a high-dielectric-constant film (TEOS) having the highest dielectric constant among the contact interlayer insulating film (11), the first interlayer insulating film (15) and the second interlayer insulating film (23),
wherein the second interlayer insulating film (23) is formed of a 25low-dielectric-constant film (porous MSQ, HSQ) having the lowest dielectric constant among the contact interlayer insulating film (11), the first interlayer insulating film (15) and the second interlayer insulating film (23), and
- 108 -wherein the first interlayer insulating film (15) is formed of a middle-dielectric-constant film (FLARE) having dielectric constant lower than that of the contact interlayer insulating film (14) and higher than that of the second interlayer insulating film (23),
wherein a dielectric constant of the high-dielectric-constant film (TEOS) is larger than or equal to 3.5,
wherein a dielectric constant of the middle-dielectric-constant film (FLARE) is larger than or equal to 2.8 and smaller than 3.5, and
wherein a dielectric constant of the low-dielectric-constant film (porous MSQ, HSQ) is smaller than 2.8. (See FIG. 13).
Therefore, it would have been obvious to one having ordinary skill in the art at the time of invention was made to form the second interlayer insulating film of HOTTA utilizing dielectric material having the lowest dielectric constant among the contact interlayer insulating film, the first interlayer insulating film and the second interlayer insulating film as taught by NOGUCHI to reduce capacity between the wiring and also leakage current.
Moreover, given a finite number of materials and their compounds, it is obvious to try without undue experimentation.
Further, it has been held to be within the general skill of a worker in the art to select a known material on the basis of it suitability for the intended use as a matter of obvious design choice. In re Leshin, 125 USPQ 416., 125 USPQ 416.
With respect to claim - 115 -23, HOTTA teaches a semiconductor device substantially as claimed including:
a semiconductor substrate (1);
a MISFET (Q) formed on the semiconductor substrate (1);
a contact interlayer insulating film (14) covering the MISFET (Q) formed 5on the semiconductor substrate (1);
a first plug (16) formed in the contact interlayer insulating film (14) and electrically connected to the MISFET (Q);
a first interlayer insulating film (17) formed on the contact interlayer insulating film;
10a first layer wiring (19) formed in the first interlayer insulating film (17) and electrically connected to the first plug (16);
a barrier insulating film formed on the first interlayer insulating film (17) and the first layer wiring (18), the barrier insulating film being formed of i) a SiCN film (21) and ii) a SiCO film (22) formed on the SiCN film (21);
a second interlayer insulating film (23) formed on the barrier insulating film such that the second interlayer insulating film (23) directly contact the barrier insulating film;
a second plug (33 plug) formed in the second interlayer insulating film (23) 15and electrically connected to the first layer wiring (19); and
a second layer wiring (33 wiring) formed in the second interlayer insulating film (23) and electrically connected to the second plug (33 plug),
wherein the contact interlayer insulating film (14) is formed of a high-Young's-modulus film (TEOS) having the highest Young's modulus among 20the contact interlayer insulating film (14), the first interlayer insulating film (17, SIOC) and the second interlayer insulating film (23),
wherein the second interlayer insulating film (23) is formed of a low-Young's-modulus film (SIOC) having the low Young's modulus among the contact interlayer insulating film (14, TEOS), the first interlayer 25insulating film (17, SIOC) and the second interlayer insulating film (23, SIOC), and
wherein the first interlayer insulating film (17, SIOC) is formed of a middle-Young's-modulus film having Young's modulus lower than that - 116 -of the contact interlayer insulating film (TEOS) and higher than that of the second interlayer insulating film (23/25),
wherein a Young's modulus of the high-Young's-modulus film (14, TEOS) is larger than or equal to 30,
wherein a Young's modulus of the middle-Young's-modulus film (17, SIOC) is smaller than 30, and
wherein a Young's modulus of the low-Young's-modulus film (23, SIOC) is smaller than 30. (See FIG. 13).
Note that, the Young's modulus or the hardness of a material is directly related to or the characteristics of, that material.
Thus, HOTA is shown to teach all the features of the claim with the exception of explicitly disclosing the first interlayer insulating film being formed of a middle-Young's-modulus film having Young's modulus lower than that - 116 -of the contact interlayer insulating film and higher than that of the second interlayer insulating film.
However, NOGUCHI teaches a semiconductor device including:
a first interlayer insulating film (15, FLARE) formed on contact interlayer insulating film (11, TEOS); 10
a barrier insulating film formed on the first interlayer insulating film (15); and
a second interlayer insulating film (23, porous MSQ, HSQ) formed on the barrier insulating film such that the second interlayer insulating film (23) directly contact the barrier insulating film;
wherein the contact interlayer insulating film (11) is formed of a high-Young's-modulus film (TEOS) having the highest Young's modulus among 20the contact interlayer insulating film (11, TEOS), the first interlayer insulating film (15, FLARE) and the second interlayer insulating film (23, porous MSQ, HSQ),
wherein the second interlayer insulating film (23) is formed of a low-Young's-modulus film (porous MSQ, HSQ) having the lowest Young's modulus among the contact interlayer insulating film (11, TEOS), the first interlayer 25insulating film (15, FLARE) and the second interlayer insulating film (23, porous MSQ, HSQ), and
wherein the first interlayer insulating film (15) is formed of a middle-Young's-modulus film (FLARE) having Young's modulus lower than that - 116 -of the contact interlayer insulating film (TEOS) and higher than that of the second interlayer insulating film (porous MSQ, HSQ),
wherein a Young's modulus of the high-Young's-modulus film (TEOS) is larger than or equal to 30,
wherein a Young's modulus of the middle-Young's-modulus film (15, FLARE) is larger than or equal to 15 and smaller than 30, and
wherein a Young's modulus of the low-Young's-modulus film (23, porous MSQ, HSQ) is smaller than 15. (See FIG. 13).
Therefore, it would have been obvious to one having ordinary skill in the art at the time of invention was made to form the first interlayer insulating film of HOTTA utilizing of a middle-Young's-modulus film having Young's modulus lower than that - 116 -of the contact interlayer insulating film and higher than that of the second interlayer insulating film as taught by NOGUCHI to reduce capacity between the wiring and also leakage current.
Moreover, given a finite number of materials and their compounds, it is obvious to try without undue experimentation.
Further, it has been held to be within the general skill of a worker in the art to select a known material on the basis of it suitability for the intended use as a matter of obvious design choice. In re Leshin, 125 USPQ 416., 125 USPQ 416.
With respect to claims 2 and 24, the high-dielectric-constant film (11) of HOTTA or NOGUCHI, is formed of either of a silicon oxide film, a SiOF film or a TEOS film,
wherein the first interlayer insulating film (17) is formed of 10either of a SiOC film, an HSQ film, or an MSQ film, and
wherein, in view of NOGUCHI, the second interlayer insulating film (23, porous) is formed of either of a SiOC film having a void, an HSQ film having a void, or an MSQ film having a void.
With respect to claims 325 and 25, the semiconductor device of HOTTA further comprises a damage protection film (34) formed on the second interlayer insulating film (23),
- 109 -wherein the damage protection film (34) is formed of a SiOC film, and
wherein the second layer wiring (33 wiring) and the second plug (33 plug) are formed to be buried in the second interlayer insulating film (23) and the damage 5protection film (34). (See FIG. 11).
With respect to claims 4 and 26, a thickness of the first interlayer insulating film (17) of HOTTA is larger than or equal to 100 nm.
With respect to claims 5 and 27, a thickness of the first interlayer insulating film (17) of HOTTA is smaller than or equal to 200 nm.
With respect to claims 6 and 28, a thickness of the first interlayer insulating film (17) of HOTTA is smaller than or equal to 200 nm.
With respect to claims 7 and 29, a thickness of the first interlayer insulating film (17) of HOTTA is larger than or equal to 100 nm.
With respect to claims 8 and 30, a thickness of the first interlayer insulating film (17) of HOTTA is smaller than or equal to 200 nm.
With respect to claims 9 and 31, a thickness of the first interlayer insulating film (17) of HOTTA is smaller than or equal to 200 nm.
With respect to claims 10 and 32, a thickness of the second interlayer insulating film (23) of HOTTA is 200 nm to 2000 nm.
With respect to claims 11 and 33, a thickness of the second interlayer insulating film (23) of HOTTA is 200 nm to 2000 nm.
With respect to claims 12 and 34, the high-dielectric-constant film (14) of HOTTA or NOGUCHI, is formed of a TEOS film.
With respect to claims 13 and 35, the high-dielectric-constant film (14) of HOTTA or NOGUCHI, is formed of the TEOS film.
With respect to claims 14 and 36, the semiconductor device of HOTTA or NOGUCHI further comprises:
a third interlayer insulating film (35 or 37) formed on the second interlayer insulating film (23);
5a third plug (43 plug) formed in the third interlayer insulating film (35); and
a third layer wiring (43 wiring) formed in the third interlayer insulating film (35) and electrically connected to the third plug (43 plug),
wherein the third interlayer insulating film (35 or 37) is formed of 10either of a SiOC film, an HSQ film, or an MSQ film. (See FIG. 14).
With respect to claims 15 and 37, the semiconductor device of HOTTA further comprising:
a fourth interlayer insulating film (45) formed on the third interlayer insulating film (35);
a fourth plug (54 plug) formed in the fourth interlayer insulating film (45);
a fourth layer wiring (45 wiring) formed on the fourth interlayer insulating film (45) and electrically connected to the fourth plug (45 plug); and
a passivation film (56) formed on the fourth layer wiring (54 wiring),
wherein the fourth layer wiring (54 wiring) is exposed from an opening portion formed to the passivation film (56), and
wherein the fourth interlayer insulating film (45) is formed of either of a silicon oxide film, a SiOF film or a TEOS film. (See FIGs. 21, 23).
With respect to claims 16 and 38, the semiconductor device of HOTTA further comprises:
a third interlayer insulating film (35) formed on the second interlayer insulating film (23);
5a third plug (43 plug) formed in the third interlayer insulating film (35); and
a third layer wiring (43 wiring) formed in the third interlayer insulating film (35) and electrically connected to the third plug (43 plug),
wherein the third interlayer insulating film (35) is formed of 10either of a SiOC film, an HSQ film, or an MSQ film. (See FIG. 14).
With respect to claims 17 and 39, the semiconductor device of HOTTA further comprising:
a fourth interlayer insulating film (45) formed on the third interlayer insulating film (35);
a fourth plug (54 plug) formed in the fourth interlayer insulating film (45);
a fourth layer wiring (45 wiring) formed on the fourth interlayer insulating film (45) and electrically connected to the fourth plug (45 plug); and
a passivation film (56) formed on the fourth layer wiring (54 wiring),
wherein the fourth layer wiring (54 wiring) is exposed from an opening portion formed to the passivation film (56), and
wherein the fourth interlayer insulating film (45) is formed of either of a silicon oxide film, a SiOF film or a TEOS film. (See FIGs. 21, 23).
With respect to claims 18 and 40, the semiconductor device of HOTTA further comprises:
a third interlayer insulating film (35) formed on the second interlayer insulating film (23);
5a third plug (43 plug) formed in the third interlayer insulating film (35); and
a third layer wiring (43 wiring) formed in the third interlayer insulating film (35) and electrically connected to the third plug (43 plug),
wherein the third interlayer insulating film (35) is formed of 10either of a SiOC film, an HSQ film, or an MSQ film. (See FIG. 14).
With respect to claims 19 and 41, the semiconductor device of HOTTA further comprising:
a fourth interlayer insulating film (45) formed on the third interlayer insulating film (35);
a fourth plug (54 plug) formed in the fourth interlayer insulating film (45);
a fourth layer wiring (45 wiring) formed on the fourth interlayer insulating film (45) and electrically connected to the fourth plug (45 plug); and
a passivation film (56) formed on the fourth layer wiring (54 wiring),
wherein the fourth layer wiring (54 wiring) is exposed from an opening portion formed to the passivation film (56), and
wherein the fourth interlayer insulating film (45) is formed of either of a silicon oxide film, a SiOF film or a TEOS film. (See FIGs. 21, 23).
With respect to claims 20 and 42, the semiconductor device of HOTTA further comprising:
a fourth interlayer insulating film (45) formed on the second interlayer insulating film (23);
a fourth plug (54 plug) formed in the fourth interlayer insulating film (45);
a fourth layer wiring (45 wiring) formed on the fourth interlayer insulating film (45) and electrically connected to the fourth plug (45 plug); and
a passivation film (56) formed on the fourth layer wiring (54 wiring),
wherein the fourth layer wiring (54 wiring) is exposed from an opening portion formed to the passivation film (56), and
wherein the fourth interlayer insulating film (45) is formed of either of a silicon oxide film, a SiOF film or a TEOS film. (See FIGs. 21, 23).
With respect to claims 21 and 43, the semiconductor device of HOTTA further comprising:
a fourth interlayer insulating film (45) formed on the second interlayer insulating film (23);
a fourth plug (54 plug) formed in the fourth interlayer insulating film (45);
a fourth layer wiring (45 wiring) formed on the fourth interlayer insulating film (45) and electrically connected to the fourth plug (45 plug); and
a passivation film (56) formed on the fourth layer wiring (54 wiring),
wherein the fourth layer wiring (54 wiring) is exposed from an opening portion formed to the passivation film (56), and
wherein the fourth interlayer insulating film (45) is formed of either of a silicon oxide film, a SiOF film or a TEOS film. (See FIGs. 21, 23).
With respect to claims 22 and 44, the semiconductor device of HOTTA further comprising:
a fourth interlayer insulating film (45) formed on the second interlayer insulating film (23);
a fourth plug (54 plug) formed in the fourth interlayer insulating film (45);
a fourth layer wiring (45 wiring) formed on the fourth interlayer insulating film (45) and electrically connected to the fourth plug (45 plug); and
a passivation film (56) formed on the fourth layer wiring (54 wiring),
wherein the fourth layer wiring (54 wiring) is exposed from an opening portion formed to the passivation film (56), and
wherein the fourth interlayer insulating film (45) is formed of either of a silicon oxide film, a SiOF film or a TEOS film. (See FIGs. 21, 23).
Conclusion
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/ANH D MAI/ Primary Examiner, Art Unit 2893