And DETAILED ACTION
The present application, filed on or after March 16, 2013, is being examined under the first inventor to file provisions of the AIA .
Claim Rejections - 35 USC § 102
The following is a quotation of the appropriate paragraphs of 35 U.S.C. 102 that form the basis for the rejections under this section made in this Office action:
A person shall be entitled to a patent unless –
(a)(1) the claimed invention was patented, described in a printed publication, or in public use, on sale, or otherwise available to the public before the effective filing date of the claimed invention.
Claim(s) 1, and 3-16, is/are rejected under 35 U.S.C. 102(a)(1) as being anticipated by U. S. Patent Application Publication No. 2021/0055652 (hereinafter referred to as Hatakeyama).
Hatakeyama, in the abstract, and in [0013]-[0014], discloses a resist composition that comprises an acid generator ([0036], photoacid generator) that contains a sulfonium salt, see below,
PNG
media_image1.png
106
445
media_image1.png
Greyscale
, wherein the aryl group bonded to the sulfonium ion, includes an acid labile substitution in the claimed manner wherein the acid labile group substitution includes an ether or carbonyl or ester bond, i.e., the X3 (claimed [O-RALU]) can be an oxygen, and is bonded to R1 (claimed Rf), wherein the R1 is a single bond and may contain an ether or ester or hydroxyl moiety (see [0047]). The R2 groups can include aryl groups (hydrocarbyl groups). The aryl group, illustrated above includes other substitution such as R3 that includes fluorine or fluorinated hydrocarbyl (see [0055]), and is the same as the claimed Rf , and includes the structures, see below,
PNG
media_image2.png
135
135
media_image2.png
Greyscale
,
PNG
media_image3.png
125
151
media_image3.png
Greyscale
,
PNG
media_image4.png
222
144
media_image4.png
Greyscale
,
PNG
media_image5.png
241
149
media_image5.png
Greyscale
and discloses the same claimed [O-RALU] group. Hatakeyama, in [0014], discloses that the X- is a non-nucleophilic counter ion such as a fluorinated sulfonate or a fluorinated imide or fluorinated methide ion and is the same counter ion as that recited (not polymerizable group) (claims 1-6). Hatakeyama, in [0015]-[0016], and in [0086]-0089], discloses that the base polymer in the resist composition includes the following recurring units (a1) and (a2), and is the same as the claimed repeating units, see (a1) and (a2) below,
PNG
media_image6.png
136
95
media_image6.png
Greyscale
PNG
media_image7.png
153
131
media_image7.png
Greyscale
, wherein the R11 and R12, are acid labile groups ([0091]), and discloses the same repeating units (see [0086]-[0094]) (claim 7). Hatakeyama, in [0095] and [0096], discloses that the base polymer further comprises recurring units that include, see below,
PNG
media_image8.png
125
98
media_image8.png
Greyscale
and is the same as the claimed (b1), and
PNG
media_image9.png
141
96
media_image9.png
Greyscale
and is the same as the claimed (b2) (claim 8). Hatakeyama, in [0099]-[0103], discloses that the base polymer includes repeating units (f) that are polymer bound onium salt, see below,
PNG
media_image10.png
107
130
media_image10.png
Greyscale
,
PNG
media_image11.png
147
168
media_image11.png
Greyscale
,
PNG
media_image12.png
113
159
media_image12.png
Greyscale
wherein Z1 can be a hydrocarbylene group or phenylene group that contains a carbonyl or ester bond, Z2 can be a single bond or carbonyl group, and Z3 is a single bond or methylene or ethylene or phenylene groups that may contain a carbonyl moiety and is the same as the claimed repeating units recited in claim 9. Hatakeyama, in [0120], discloses that the resist composition includes an organic solvent and other components such as an onium salt (see [0125]-[0128]), that includes the following structures, see below,
PNG
media_image13.png
73
173
media_image13.png
Greyscale
wherein R101, and R102 , are hydrocarbyl groups (see [0127]) (claim 11). Hatakeyama, in [0020], and [0124], discloses that the resist composition includes a surfactant and an amine compound (claims 13-14). Hatakeyama, in [0021]-[0020], discloses that the resist composition is applied to a substrate to form a resist film, exposing the resist film to high energy radiation such as DUV, or EB or EUV, and developing the exposed resist film in a developer (claims 15-16).
Response to Arguments
Applicant's arguments filed April 15, 2026, have been fully considered but they are not persuasive. The 35 U.S.C. 102(a)(1) rejection made over pending claims has been maintained. The Terminal Disclaimer filed April 15, 2026, has overcome the nonstatutory double patenting rejection made over claims 1-16 in the previous office action. With respect to applicant’s argument that Hatakeyama does not disclose the claimed ALU groups, and that the compounds by Hatakeyama falls outside the scope of the amended claim 1, Hatakeyama, in [0041]-[0047], and [0055], discloses the general formula of the sulfonium salt, see below,
PNG
media_image14.png
146
604
media_image14.png
Greyscale
wherein X3 can be an ether bond i.e., -O-, and R1 can be a branched alkyl and includes a t-butyl group (claimed C(R21, R22, and R23)), and R3 (same as the claimed Rf) can be a fluorine atom and applicant’s ALU groups recite that “u” and “v” can be zero, and that claimed R22 is a hydrocarbyl with an optional substituent. For ALU groups, when “v” and/or “u” =0, the ALU groups, as discussed in the preceding sentence, is within scope of the claimed sulfonium salt structure recited in the claim. Therefore, the rejection is maintained.
Conclusion
THIS ACTION IS MADE FINAL. Applicant is reminded of the extension of time policy as set forth in 37 CFR 1.136(a).
A shortened statutory period for reply to this final action is set to expire THREE MONTHS from the mailing date of this action. In the event a first reply is filed within TWO MONTHS of the mailing date of this final action and the advisory action is not mailed until after the end of the THREE-MONTH shortened statutory period, then the shortened statutory period will expire on the date the advisory action is mailed, and any nonprovisional extension fee (37 CFR 1.17(a)) pursuant to 37 CFR 1.136(a) will be calculated from the mailing date of the advisory action. In no event, however, will the statutory period for reply expire later than SIX MONTHS from the mailing date of this final action.
Any inquiry concerning this communication or earlier communications from the examiner should be directed to Daborah Chacko-Davis whose telephone number is (571) 272-1380. The examiner can normally be reached on 9:30AM-6:00PM EST Mon-Fri. If attempts to reach the examiner by telephone are unsuccessful, the examiner’s supervisor, Sally A. Merkling can be reached on (571) 272-6297. The fax phone number for the organization where this application or proceeding is assigned is 571-272-8300. Information regarding the status of published or unpublished applications may be obtained from Patent Center. Unpublished application information in Patent Center is available to registered users. To file and manage patent submissions in Patent Center, visit: https://patentcenter.uspto.gov. Visit https://www.uspto.gov/patents/apply/patent-center for more information about Patent Center and https://www.uspto.gov/patents/docx for information about filing in DOCX format. For additional questions, contact the Electronic Business Center (EBC) at 866-217-9197 (toll-free). If you would like assistance from a USPTO Customer Service Representative, call 800-786-9199 (IN USA OR CANADA) or 571-272-1000.
/DABORAH CHACKO-DAVIS/Primary Examiner, Art Unit 1737 June 17, 2026.